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Weight Change Mechanism of Lanthanum Strontium Manganite (LSM) During Thermal Cycles

  • Advances in Reversible Solid Oxide Electrochemical Cells for Energy Conversion
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Abstract

In the current work, the weight change behavior of (La0.8Sr0.2)0.98MnO3 ± δ (LSM-20) from room temperature to 1100°C during the thermal cycle experiments in dry air and Ar was comprehensively investigated with SDT, XRD analysis, and CALPHAD. Especially the quantitative Brouwer diagrams help in understanding the defect reactions inside LSM-20. The weight change was attributed mainly to the Schottky defect reaction. The relationship among weight change, molar change, defect reactions, chemical expansion, and phase transformation is discussed in detail. It is proposed that two very close rhombohedral LT and HT perovskites coexist in our thermal cycle temperature range. Also, the role of P(O2) in the thermal cycle shrinkage is discussed.

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Acknowledgement

This work is supported by the Worcester Polytechnic Institute startup funding.

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Authors and Affiliations

  1. Mechanical and Materials Engineering Department, Worcester Polytechnic Institute, Worcester, MA, 01609, USA

    Yu Zhong, Rui Wang, Hooman Sabarou & Yashdi Saif Autul

  2. Center for the Study of Matter at Extreme Conditions, Department of Mechanical and Material Engineering, Florida International University, Miami, FL, 33199, USA

    Vadym Drozd

  3. Materials Science and Engineering, Oklahoma State University, Tulsa, OK, 74106, USA

    Dan Lowry & Sarin Pankaj

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  1. Yu Zhong
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Zhong, Y., Wang, R., Drozd, V. et al. Weight Change Mechanism of Lanthanum Strontium Manganite (LSM) During Thermal Cycles. JOM 74, 4533–4543 (2022). https://doi.org/10.1007/s11837-022-05535-2

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